A promising 1D Cd-based hybrid perovskite-type for white-light emission with high-color-rendering index.

ABSTRACT: A one dimensional (1D) perovskite-type (C₆H₇NBr)₃[CdBr₅] (abbreviated 4-BAPC) was synthesized by slow evaporation at room temperature (RT). 4-BAPC crystalizes in the monoclinic system with the space group P2₁/c. The 1D inorganic chains are formed by corner sharing CdBr₆ octahedra. Thermal measurement shows that 4-BAPC is stable up to 190 °C. Optical characterization demonstrates that the grown crystal is an indirect bandgap material with a bandgap value of 3.93 eV, which is consistent with theoretical calculations. The electronic structure, calculated using density functional theory, reveals that the valence band originates from a combination of Br-4p orbitals and Cd-4d orbitals, whereas the conduction band ori

SUBMITTER: Gassara M 

PROVIDER: S-EPMC9682491 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature