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The Synergistic Effect of Adsorption-Photocatalysis for Removal of Organic Pollutants on Mesoporous Cu2V2O7/Cu3V2O8/g-C3N4 Heterojunction.


ABSTRACT: Cu2V2O7/Cu3V2O8/g-C3N4 heterojunctions (CVCs) were prepared successfully by the reheating synthesis method. The thermal etching process increased the specific surface area. The formation of heterojunctions enhanced the visible light absorption and improved the separation efficiency of photoinduced charge carriers. Therefore, CVCs exhibited superior adsorption capacity and photocatalytic performance in comparison with pristine g-C3N4 (CN). CVC-2 (containing 2 wt% of Cu2V2O7/Cu3V2O8) possessed the best synergistic removal efficiency for removal of dyes and antibiotics, in which 96.2% of methylene blue (MB), 97.3% of rhodamine B (RhB), 83.0% of ciprofloxacin (CIP), 86.0% of tetracycline (TC) and 80.5% of oxytetracycline (OTC) were eliminated by the adsorption and photocatalysis synergistic effect under visible light irradiation. The pseudo first order rate constants of MB and RhB photocatalytic degradation on CVC-2 were 3 times and 10 times that of pristine CN. For photocatalytic degradation of CIP, TC and OTC, it was 3.6, 1.8 and 6.1 times that of CN. DRS, XPS VB and ESR results suggested that CVCs had the characteristics of a Z-scheme photocatalytic system. This study provides a reliable reference for the treatment of real wastewater by the adsorption and photocatalysis synergistic process.

SUBMITTER: Feng J 

PROVIDER: S-EPMC9693244 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature

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The Synergistic Effect of Adsorption-Photocatalysis for Removal of Organic Pollutants on Mesoporous Cu<sub>2</sub>V<sub>2</sub>O<sub>7</sub>/Cu<sub>3</sub>V<sub>2</sub>O<sub>8</sub>/g-C<sub>3</sub>N<sub>4</sub> Heterojunction.

Feng Jian J   Ran Xia X   Wang Li L   Xiao Bo B   Lei Li L   Zhu Jinming J   Liu Zuoji Z   Xi Xiaolan X   Feng Guangwei G   Dai Zeqin Z   Li Rong R  

International journal of molecular sciences 20221117 22


Cu<sub>2</sub>V<sub>2</sub>O<sub>7</sub>/Cu<sub>3</sub>V<sub>2</sub>O<sub>8</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions (CVCs) were prepared successfully by the reheating synthesis method. The thermal etching process increased the specific surface area. The formation of heterojunctions enhanced the visible light absorption and improved the separation efficiency of photoinduced charge carriers. Therefore, CVCs exhibited superior adsorption capacity and photocatalytic performance in compari  ...[more]

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