Modeling historical budget for β-Hexachlorocyclohexane (HCH) in the Arctic Ocean: A contrast to α-HCH.

ABSTRACT: The historical annual loading to, removal from, and cumulative burden in the Arctic Ocean for β-hexachlorocyclohexane (β-HCH), an isomer comprising 5-12% of technical HCH, is investigated using a mass balance box model from 1945 to 2020. Over the 76 years, loading occurred predominantly through ocean currents and river inflow (83%) and only a small portion via atmospheric transport (16%). β-HCH started to accumulate in the Arctic Ocean in the late 1940s, reached a peak of 810 t in 1986, and decreased to 87 t in 2020, when its concentrations in the Arctic water and air were ∼30 ng m^-3 and ∼0.02 pg m^-3, respectively. Even though β-HCH and α-HCH (60-70% of technical HCH) are both the isomers of HCHs with almost identical temporal and spatial emission patterns, these two

SUBMITTER: Yang PF 

PROVIDER: S-EPMC9755237 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature