Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)-Centre: Labile Mono- and Bis(hydridogallyl)zinc Complexes.

ABSTRACT: In the presence of TMEDA (N,N,N',N'-tetramethylethylenediamine), partially deaggregated zinc dihydride as hydrocarbon suspensions react with the gallium(I) compound [(BDI)Ga] (I, BDI={HC(C(CH₃ )N(2,6-iPr₂ -C₆ H₃ ))₂ }^- ) by formal oxidative addition of a Zn-H bond to the gallium(I) centre. Dissociation of the labile TMEDA ligand in the resulting complex [(BDI)Ga(H)-(H)Zn(tmeda)] (1) facilitates insertion of a second equiv. of I into the remaining Zn-H to form a thermally sensitive trinuclear species [{(BDI)Ga(H)}₂ Zn] (2). Compound 1 exchanges with polymeric zinc dideuteride [ZnD₂ ]_n in the presence of TMEDA, and with compounds I and 2 via sequential and reversible ligand dissociation and gal

SUBMITTER: Morris LJ 

PROVIDER: S-EPMC9804236 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature