B(C₆ F₅ )₃ -Catalyzed E-Selective Isomerization of Alkenes.

ABSTRACT: Herein, we report the B(C₆ F₅ )₃ -catalyzed E-selective isomerization of alkenes. The transition-metal-free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.

SUBMITTER: Kustiana BA 

PROVIDER: S-EPMC9804281 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature