Surface modifications of eight-electron palladium silver superatomic alloys.

ABSTRACT: Atomically precise thiolate-protected coinage metal nanoclusters and their alloys are far more numerous than their selenium congeners, the synthesis of which remains extremely challenging. Herein, we report the synthesis of a series of atomically defined dithiophosph(in)ate protected eight-electron superatomic palladium silver nanoalloys [PdAg₂₀{S₂PR₂}₁₂], 2a-c (where R = OⁱPr, a; OⁱBu, b; Ph, c) via ligand exchange and/or co-reduction methods. The ligand exchange reaction on [PdAg₂₀{S₂P(OⁿPr)₂}₁₂], 1, with [NH₄{Se₂PR₂}₁₂] (where R = OⁱPr, or OⁿPr) leads to the formation of [PdAg₂₀{Se₂

SUBMITTER: Barik SK 

PROVIDER: S-EPMC9814913 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature