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Anisotropic Wooden Electromechanical Transduction Devices Enhanced by TEMPO Oxidization and PDMS.

ABSTRACT: In order to increase the number and contact probability of electric dipole on cellulose, acid and alkali treatment was employed to extract hemicellulose and lignin from original wood to gain a highly oriented cellulose frame. The combined means with 2,2,6,6-tetramethylpiperidine-1-oxyl-NaBr-NaClO oxidation and impregnation of PDMS with compression was subsequently used to enhance its mechanical performance and electromechanical conversion. The assembled wooden electromechanical device (10 mm × 10 mm × 1 mm) exhibits the maximum open-circuit voltage (V _OC) of 11.75 V and short-circuit current (I _SC) of 211.01 nA as stepped by foot. It can be sliced to fabricate a flexible sensor with high sensitivity displaying V _OC of 2.88 V and I _SC of 210.09 nA under the tapped state. Its highly oriented wood fiber makes it display significant anisotropy in terms of mechanical and electromechanical performance for multidirectional sense. This strategy will exactly provide reference for developing other high-performance piezoelectric devices.

SUBMITTER: Jiang B

PROVIDER: S-EPMC9893449 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Anisotropic Wooden Electromechanical Transduction Devices Enhanced by TEMPO Oxidization and PDMS.

Jiang Bei B Li Meilin M Cao Shuoang S Wang Zining Z Huang Lijun L Song Xinyi X Zhang Yuanqiao Y Yuan Quanping Q

ACS omega 20230120 4

In order to increase the number and contact probability of electric dipole on cellulose, acid and alkali treatment was employed to extract hemicellulose and lignin from original wood to gain a highly oriented cellulose frame. The combined means with 2,2,6,6-tetramethylpiperidine-1-oxyl-NaBr-NaClO oxidation and impregnation of PDMS with compression was subsequently used to enhance its mechanical performance and electromechanical conversion. The assembled wooden electromechanical device (10 mm × 1 ...[more]

PMID: 36743053

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Project description:Polydimethylsiloxane (PDMS), a silicone elastomer, is increasingly being used in health and biomedical fields due to its excellent optical and mechanical properties. Its biocompatibility and resistance to biodegradation led to various applications (e.g., lung on a chip replicating blood flow, medical interventions, and diagnostics). The many advantages of PDMS are, however, partially offset by its inherent hydrophobicity, which makes it unsuitable for applications needing wetting, thus requiring the hydrophilization of its surface by exposure to UV or O2 plasma. Yet, the elastomeric state of PDMS translates in a slow, hours to days, process of reducing its surface hydrophilicity-a process denominated as hydrophobic recovery. Using Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM), the present study details the dynamics of hydrophobic recovery of PDMS, on flat bare surfaces and on surfaces embedded with hydrophilic beads. It was found that a thin, stiff, hydrophilic, silica film formed on top of the PDMS material, following its hydrophilization by UV radiation. The hydrophobic recovery of bare PDMS material is the result of an overlap of various nano-mechanical, and diffusional processes, each with its own dynamics rate, which were analyzed in parallel. The hydrophobic recovery presents a hysteresis, with surface hydrophobicity recovering only partially due to a thin, but resilient top silica layer. The monitoring of hydrophobic recovery of PDMS embedded with hydrophilic beads revealed that this is delayed, and then totally stalled in the few-micrometer vicinity of the embedded hydrophilic beads. This region where the hydrophobic recovery stalls can be used as a good approximation of the depth of the resilient, moderately hydrophilic top layer on the PDMS material. The complex processes of hydrophilization and subsequent hydrophobic recovery impact the design, fabrication, and operation of PDMS materials and devices used for diagnostics and medical procedures. Consequently, especially considering the emergence of new surgical procedures using elastomers, the impact of hydrophobic recovery on the surface of PDMS warrants more comprehensive studies.

Dataset Information

Anisotropic Wooden Electromechanical Transduction Devices Enhanced by TEMPO Oxidization and PDMS.

Publications

Anisotropic Wooden Electromechanical Transduction Devices Enhanced by TEMPO Oxidization and PDMS.

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