Crystallinity Tuning of Na₃ V₂ (PO₄ )₃ : Unlocking Sodium Storage Capacity and Inducing Pseudocapacitance Behavior.

ABSTRACT: As a promising cathode material of sodium-ion batteries, Na₃ V₂ (PO₄ )₃ (NVP) has attracted extensive attention in recent years due to its high stability and fast Na⁺ ion diffusion. However, the reversible capacity based on the two-electron reaction mechanism is not satisfactory limited by the inactive M1 lattice sites during the insertion/extraction process. Herein, self-supporting 3D porous NVP materials with different crystallinity are fabricated on carbon foam substrates by a facile electrostatic spray deposition method. The V⁵⁺ /V⁴⁺ redox couple is effectively activated and the three-electron reactions are realized in NVP for sodium storage by a proper crystallinity tuning. In a disordered NVP sample, an ultr

SUBMITTER: Ma H 

PROVIDER: S-EPMC9896047 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature