Dataset Information

Identification of Cadmium Compounds in a Solution Using Graphene-Based Sensor Array.

ABSTRACT: Rapid detection of heavy metals in solution is necessary to ensure human health and environmental protection. Some heavy-metal compounds are present in solution as compounds instead of as ions owing to their low ionization. Therefore, the development of sensor devices for the detection of heavy-metal compounds is important. In this study, as a proof of concept, we propose a sensor device using graphene and a chelating agent, which were used to develop an identification technique for three types of cadmium compounds. Pristine-graphene and two types of chelator-modified graphene-based sensors were successfully used to detect cadmium compounds at concentrations ranging from 50 to 1000 μM. The detection time was less than 5 min. The three type of graphene-based sensors responded differently to each cadmium compound, which indicates that they detected cadmium as a cadmium compound instead of as cadmium ions. Furthermore, we successfully identified cadmium compounds by operating these three types of sensors as a sensor array on the same substrate. The results indicate that sensors that focus on heavy-metal compounds instead of heavy-metal ions can be used for the detection of heavy metals in solution.

SUBMITTER: Yoshii T

PROVIDER: S-EPMC9921919 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Identification of Cadmium Compounds in a Solution Using Graphene-Based Sensor Array.

Yoshii Tomoya T Nishitsugu Fuka F Kikawada Kazuki K Maehashi Kenzo K Ikuta Takashi T

Sensors (Basel, Switzerland) 20230130 3

Rapid detection of heavy metals in solution is necessary to ensure human health and environmental protection. Some heavy-metal compounds are present in solution as compounds instead of as ions owing to their low ionization. Therefore, the development of sensor devices for the detection of heavy-metal compounds is important. In this study, as a proof of concept, we propose a sensor device using graphene and a chelating agent, which were used to develop an identification technique for three types ...[more]

PMID: 36772559

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Project description:A typical lock-and-key sensing strategy, relying only on the most dominant interactions between the probe and target, could be too limiting. In reality, the information received upon sensing is much richer. Non-specific events due to various intermolecular forces contribute to the overall received information with different degrees, and when analyzed, could provide a much more powerful detection opportunity. Here, we have assembled a highly selective universal sensor array using water-soluble two-dimensional nanoparticles (nGO, MoS2 and WS2) and fluorescent DNA molecules. The array is composed of 12 fluorescently silent non-specific nanoreceptors (2D-nps) and used for the identification of three radically different systems; five proteins, three types of live breast cancer cells and a structure-switching event of a macromolecule. The data matrices for each system were processed using Partial Least Squares (PLS) discriminant analysis. In all of the systems, the sensor array was able to identify each object or event as separate clusters with 95% confidence and without any overlap. Out of 15 unknown entities with unknown protein concentrations tested, 14 of them were predicted successfully with correct concentration. 8 breast cancer cell samples out of 9 unknown entities from three cell types were predicted correctly. During the assembly of each nanoprobe, the intrinsic non-covalent interactions between unmodified 2D nanoparticles and ssDNAs were exploited. The unmodified 2D materials offer remarkable simplicity in the layout and the use of ssDNAs as probes provides limitless possibilities because the natural interaction of a ssDNA and 2D surface can be fine-tuned with the nucleobase composition, oligonucleotide length and type of 2D nanomaterial. Therefore, the approach described here can be advanced and fine-tuned indefinitely for meeting a particular sensing criterion. Though we have only studied three distinct elements, this approach is universal enough to be applied to a wide-range of systems.

Dataset Information

Identification of Cadmium Compounds in a Solution Using Graphene-Based Sensor Array.

Publications

Identification of Cadmium Compounds in a Solution Using Graphene-Based Sensor Array.

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