Non-covalent ligand-oxide interaction promotes oxygen evolution.

ABSTRACT: Strategies to generate high-valence metal species capable of oxidizing water often employ composition and coordination tuning of oxide-based catalysts, where strong covalent interactions with metal sites are crucial. However, it remains unexplored whether a relatively weak "non-bonding" interaction between ligands and oxides can mediate the electronic states of metal sites in oxides. Here we present an unusual non-covalent phenanthroline-CoO₂ interaction that substantially elevates the population of Co⁴⁺ sites for improved water oxidation. We find that phenanthroline only coordinates with Co²⁺ forming soluble Co(phenanthroline)₂(OH)₂ complex in alkaline electrolytes, which can be deposited as amorphous CoO_xH_y film

SUBMITTER: Wu Q 

PROVIDER: S-EPMC9947139 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature