Order-disorder charge density wave instability in the kagome metal (Cs,Rb)V₃Sb₅.

ABSTRACT: The origin of the charge density wave phases in the kagome metal compound AV₃Sb₅ is still under great scrutiny. Here, we combine diffuse and inelastic x-ray scattering to identify a 3-dimensional precursor of the charge order at the L point that condenses into a CDW through a first order phase transition. The quasi-elastic critical scattering indicates that the dominant contribution to the diffuse precursor is the elastic central peak without phonon softening. However, the inelastic spectra show a small broadening of the Einstein-type phonon mode on approaching T_CDW. Our results point to the situation where the Fermi surface instability at the L point is of order-disorder type with critical growth of quasi-static domains. The experimental data indicate that the CDW consists on an alternating Star of David and trihexagonal distortions and its dynamics goes beyond the classical weak-coupling scenario and is discussed within strong-electron phonon coupling and non-adiabatic models.

SUBMITTER: Subires D 

PROVIDER: S-EPMC9950456 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature