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Removing unreacted amino groups in graphitic carbon nitride through residual heating to improve the photocatalytic performance.

ABSTRACT: In most of the research about graphitic carbon nitride (g-C₃N₄), g-C₃N₄ is prepared through the calcination of nitrogen-rich precursors. However, such a preparation method is time-consuming, and the photocatalytic performance of pristine g-C₃N₄ is lackluster due to the unreacted amino groups on the surface of g-C₃N₄. Therefore, a modified preparation method, calcination through residual heating, was developed to achieve rapid preparation and thermal exfoliation of g-C₃N₄ simultaneously. Compared with pristine g-C₃N₄, the samples prepared by residual heating had fewer residual amino groups, a thinner 2D structure, and higher crystallinity, which led to a better photocatalytic performance. The photocatalytic degradation rate of the optimal sample for rhodamine B could reach 7.8 times higher than that of pristine g-C₃N₄.

SUBMITTER: Zhang WJ

PROVIDER: S-EPMC9969336 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Removing unreacted amino groups in graphitic carbon nitride through residual heating to improve the photocatalytic performance.

Zhang Wen-Jun WJ Wang Feng-Jue FJ Liu Han H Wang Yue Y Chen Meng M

RSC advances 20230227 10

In most of the research about graphitic carbon nitride (g-C3N4), g-C3N4 is prepared through the calcination of nitrogen-rich precursors. However, such a preparation method is time-consuming, and the photocatalytic performance of pristine g-C3N4 is lackluster due to the unreacted amino groups on the surface of g-C3N4. Therefore, a modified preparation method, calcination through residual heating, was developed ...[more]

PMID: 36860530

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Project description:Graphitic carbon nitride (GCN), as a promising photocatalyst, has been intensely investigated in the photocatalytic fields, but its performance is still unsatisfactory. To date, metal ion doping has been proven to be an effective modification method to improve the photocatalytic activity of GCN. More importantly, comprehensive understanding of the doping mechanism will be of benefit to synthesize efficient GCN based photocatalysts. In this work, K+-doped GCN samples were prepared via heating the mixture of the preheated melamine and a certain amount of KCl at different synthetic temperatures. XRD and Raman characterization studies indicated that the introduction of K+ could improve its crystallinity at higher temperature but reduce its crystallinity at lower temperature. Moreover, FTIR and SEM-EDS measurements implied that K+ are found dominantly in the surface of the ion-doped sample prepared at lower temperature, while they are found both in the surface and bulk of the ion-doped sample prepared at higher temperature. These observations revealed that K+ distributed in the surface of the ion-doped GCN could inhibit its crystal growth, while K+ distributed inside of the ion-doped GCN could promote its crystallinity. Owing to the greater inducing effect of the bulk K+ than the disturbing effect of the surface K+, the improvement of the crystallinity for K+-doped GCN was achieved. As a result, the K+-doped GCN with higher crystallinity yielded an obviously higher H2 evolution rate than that with lower crystallinity under visible light irradiation (>420 nm). Besides, it was observed that the K+-doped GCN prepared at higher temperature exhibits significantly greater adsorption capacity for methylene blue than the K+-doped GCN prepared at lower temperature. This work would provide an insight into optimizing metal ion doped GCN with high photocatalytic activity. The greater inducing effect than the disturbing effect of K ions results in the improved crystallinity and enhanced photocatalytic hydrogen evolution activity of graphitic carbon nitride.

Dataset Information

Removing unreacted amino groups in graphitic carbon nitride through residual heating to improve the photocatalytic performance.

Publications

Removing unreacted amino groups in graphitic carbon nitride through residual heating to improve the photocatalytic performance.

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