MOF-Triggered Synthesis of Subnanometer Ag⁰₂ Clusters and Fe³⁺ Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions.

ABSTRACT: The combination of well-defined Fe³⁺ isolated single-metal atoms and Ag₂ subnanometer metal clusters within the channels of a metal-organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction for the first time. The resulting hybrid material, with the formula [Ag⁰₂(Ag⁰)_1.34Fe^III_0.66]@Na^I₂{Ni^II₄[Cu^II₂(Me₃mpba)₂]₃}·63H₂O (Fe³⁺Ag⁰₂@MOF), is capable of catalyzing the unprecedented direct conversion of styrene to phenylacetylene in one pot. In particular, Fe³⁺Ag

SUBMITTER: Tiburcio E 

PROVIDER: S-EPMC10176469 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature