Dataset Information

From K₆[Re_6-xMo_xS₈(CN)₅] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re₄Mo₂S₈(CN)₆]^n- and [Re₃Mo₃S₈(CN)₆]^n- Heterometallic Clusters.

ABSTRACT: A series of new cluster compounds with {Re₄Mo₂S₈} and {Re₃Mo₃S₈} cores has been obtained and investigated. The clusters with different Re/Mo ratios were isolated as individual compounds, which made it possible to study their spectroscopic and electrochemical properties. The geometry of the new clusters was studied using a combination of X-ray diffraction analysis, XAS and quantum chemical DFT calculations. It was shown that the properties of the new clusters, such as the number and position of electrochemical transitions, electronic structure and change in geometry with a change in charge, are similar to the properties of clusters based on the {Re₄Mo₂Se₈} and {Re₃Mo₃Se₈} cores described earlier.

SUBMITTER: Lappi TI

PROVIDER: S-EPMC10421489 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature

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From K6[Re6-xMoxS8(CN)5] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re4Mo2S8(CN)6]n- and [Re3Mo3S8(CN)6]n- Heterometallic Clusters.

Lappi Tatiana I TI Gayfulin Yakov M YM Renaud Adèle A Prestipino Carmelo C Lemoine Pierric P Yanshole Vadim V VV Muravieva Viktoria K VK Cordier Stéphane S Naumov Nikolai G NG

Molecules (Basel, Switzerland) 20230804 15

A series of new cluster compounds with {Re4Mo2S8} and {Re3Mo3S8} cores has been obtained and investigated. The clusters with different Re/Mo ratios were isolated as individual compounds, which made it possible to study their spectroscopic and electrochemical properties. The geometry of the new clusters was studied using a combination of X-ray diffraction analysis, XAS and quantum chemical DFT calculations. It was shown that the pr ...[more]

PMID: 37570845

Dataset Information

From K₆[Re_6-xMo_xS₈(CN)₅] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re₄Mo₂S₈(CN)₆]^n- and [Re₃Mo₃S₈(CN)₆]^n- Heterometallic Clusters.

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