Crystal structure and Hirshfeld surface analysis of bis-{(Z)-N'-[(E)-(furan-2-yl)methyl-idene]carbamo-hydrazono-thio-ato}nickel(II) methanol disolvate.

ABSTRACT: In the title complex, [Ni(C₆H₆N₃OS)₂]·2CH₃OH, the Ni^II atom is coordinated by the S and N atoms of two N'-[(Z)-(furan-2-yl)methyl-idene]carbamohydrazono-thioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to Ni^II are also connected by C-H⋯S inter-actions, while the H atoms of the NH₂ group of the ligands form R ⁴ ₄(8) motifs with the O atoms of the solvent ethyl alcohol mol-ecules. At the same time, the OH groups of the solvent ethyl alcohol mol-ecules form parallel layers to the (011) plane by the O-H⋯N inter-actions with the ligand N atom that is not bonded to the Ni^II atom.. The layers are connected by van der W

SUBMITTER: Azizova AN 

PROVIDER: S-EPMC10439423 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature