Unknown

Dataset Information

0

Synthesis, crystal structure and Hirshfeld surface analysis of the hybrid salt bis-(2-methyl-imidazo[1,5-a]pyridin-2-ium) tetra-chlorido-manganate(II).

ABSTRACT: The 0-D hybrid salt bis-(2-methyl-imidazo[1,5-a]pyridin-2-ium) tetra-chlorido-manganate(II), (C8H9N2)2[MnCl4] or [L]2[MnCl4], consists of discrete L + cations and tetra-chlorido-manganate(II) anions. The fused heterocyclic rings in the two crystallographically non-equivalent monovalent organic cations are almost coplanar; the bond lengths are as expected. The tetra-hedral MnCl4 2- dianion is slightly distorted with the Mn-Cl bond lengths varying from 2.3577 (7) to 2.3777 (7) Å and the Cl-Mn-Cl angles falling in the range 105.81 (3)-115.23 (3)°. In the crystal, the compound demonstrates a pseudo-layered arrangement of separate organic and inorganic sheets alternating parallel to the bc plane. In the organic layer, pairs of centrosymmetrically related trans-oriented L + cations are π-stacked. Neighboring MnCl4 2- dianions in the inorganic sheet show no connectivity, with the minimal Mn⋯Mn distance exceeding 7 Å. The Hirshfeld surface analysis revealed the prevalence of the non-conventional C-H⋯Cl-Mn hydrogen bonding in the crystal packing.

SUBMITTER: Vassilyeva OY 

PROVIDER: S-EPMC10088312 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis, crystal structure and Hirshfeld surface analysis of the hybrid salt bis-(2-methyl-imidazo[1,5-<i>a</i>]pyridin-2-ium) tetra-chlorido-manganate(II).

Vassilyeva Olga Yu OY   Buvaylo Elena A EA   Kokozay Vladimir N VN   Skelton Brian W BW  

Acta crystallographica. Section E, Crystallographic communications 20230328 Pt 4

The 0-D hybrid salt bis-(2-methyl-imidazo[1,5-<i>a</i>]pyridin-2-ium) tetra-chlorido-manganate(II), (C<sub>8</sub>H<sub>9</sub>N<sub>2</sub>)<sub>2</sub>[MnCl<sub>4</sub>] or [<i>L</i>]<sub>2</sub>[MnCl<sub>4</sub>], consists of discrete <i>L</i> <sup>+</sup> cations and tetra-chlorido-manganate(II) anions. The fused heterocyclic rings in the two crystallographically non-equivalent monovalent organic cations are almost coplanar; the bond lengths are as expected. The tetra-hedral MnCl<sub>4</sub>  ...[more]

Similar Datasets

Unknown 2-({[(Pyridin-1-ium-2-ylmeth-yl)carbamo-yl]form-amido}-meth-yl)pyridin-1-ium bis-(3,5-di-carb-oxy-benzoate): crystal structure and Hirshfeld surface analysis.
| S-EPMC4770948 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of bis­{(Z)-N′-[(E)-(furan-2-yl)methyl­idene]carbamo­hydrazono­thio­ato}nickel(II) methanol disolvate
| S-EPMC10439423 | biostudies-literature
Unknown Synthesis, crystal structure and Hirshfeld surface analysis of naphthalene-2,3-diyl bis­(3-benz­yl­oxy)benzoate
| S-EPMC10439419 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of 3,4-dihydro-2-(2,4-dioxo-6-methylpyran-3-ylidene)-4-(4-pyridin-4-yl)-1,5-benzodiazepine.
| S-EPMC6323877 | biostudies-literature
Unknown Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ4-glutarato)dicopper(II)]
| S-EPMC10561227 | biostudies-literature
Unknown Synthesis, crystal structure and Hirshfeld surface analysis of bis-{2-[(pyridin-2-yl)amino]-pyridinium} tetra-cyano-nickelate(II).
| S-EPMC7643237 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of (E)-4-{[2-(4-hy-droxy-benzo-yl)hydrazin-1-yl-idene]meth-yl}pyridin-1-ium nitrate.
| S-EPMC5947795 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of 5-methyl-1,2,4-triazolo[1,5-a]pyrimidine.
| S-EPMC6281126 | biostudies-literature
Unknown Organic-inorganic hybrid hexa-chlorido-stannate(IV) with 2-methyl-imidazo[1,5-<i>a</i>]pyridin-2-ium cation.
| S-EPMC9912472 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of a pyridiniminium bromide salt: 1-[2-(adamantan-1-yl)-2-oxoeth-yl]pyridin-4-iminium bromide.
| S-EPMC6038631 | biostudies-literature