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[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.

ABSTRACT: In the title salt, [ZnCl(C23H30N4)]NO3, the central ZnII atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen.

SUBMITTER: Ichimaru Y 

PROVIDER: S-EPMC11299653 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature

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[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.

Ichimaru Yoshimi Y   Sugiura Kirara K   Kato Koichi K   Kondo Yuki Y   Kurihara Masaaki M   Jin Wanchun W   Imai Masanori M   Kurosaki Hiromasa H  

IUCrData 20240712 Pt 7

In the title salt, [ZnCl(C<sub>23</sub>H<sub>30</sub>N<sub>4</sub>)]NO<sub>3</sub>, the central Zn<sup>II</sup> atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in  ...[more]

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