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Functional group compatibility. Propargyl alcohol reduction in the presence of a vinyl iodide.

ABSTRACT: Vinyl iodides are stable to the reduction of propargyl alcohols to cis allylic alcohols by hydrogen over Pd/CaCO(3) in hexane. They are also stable to the reduction of propargyl alcohols to saturated alcohols by hydrogen over Crabtree's iridium catalyst in CH(2)Cl(2).

SUBMITTER: Denton RW

PROVIDER: S-EPMC2726658 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Functional group compatibility. Propargyl alcohol reduction in the presence of a vinyl iodide.

Denton Richard W RW Parker Kathlyn A KA

Organic letters 20090701 13

Vinyl iodides are stable to the reduction of propargyl alcohols to cis allylic alcohols by hydrogen over Pd/CaCO(3) in hexane. They are also stable to the reduction of propargyl alcohols to saturated alcohols by hydrogen over Crabtree's iridium catalyst in CH(2)Cl(2). ...[more]

PMID: 19476372

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