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Di-μ-thio-semicarbazide-κS:S-bis-[bis-(thio-semicarbazide-κS)copper(I)] diiodide.

ABSTRACT: The title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any direct inter-action with the metal. The crystal structure is stabilized by weak N-H⋯N, N-H⋯S and N-H⋯I hydrogen bonds, forming a three-dimensional network structure.

SUBMITTER: Jia L 

PROVIDER: S-EPMC2961471 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Di-μ-thio-semicarbazide-κS:S-bis-[bis-(thio-semicarbazide-κS)copper(I)] diiodide.

Jia Li L   Ma Shou-Xin SX   Li Da-Cheng DC  

Acta crystallographica. Section E, Structure reports online 20080517 Pt 6

The title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any direct inter-action with the metal. The crystal structure is stabilized by weak N-H⋯N, N-H⋯S and N-H⋯I  ...[more]

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