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Bis(bicyclo-[2.2.1]hept-5-ene-2-carboxyl-ato)-1?O,O';4?O,O'-di-?(2)-chlorido-1:2?Cl;3:4?Cl-octa-methyl-1?C,2?C,3?C,4?C-di-?(3)-oxido-1:2:3?O;2:3:4?O-tetra-tin(IV).

ABSTRACT: In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetra-nuclear complex mol-ecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal-bipyramidal, whilst the two peripheral metal atoms bonded to the carboxyl-ate groups have a distorted octa-hedral coordination geometry. In the crystal, mol-ecules are connected by long Sn?O contacts [3.139?(11)?Å], forming chains along [011].

SUBMITTER: Ren Y

PROVIDER: S-EPMC3152064 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Bis(bicyclo-[2.2.1]hept-5-ene-2-carboxyl-ato)-1κO,O';4κO,O'-di-μ(2)-chlorido-1:2κCl;3:4κCl-octa-methyl-1κC,2κC,3κC,4κC-di-μ(3)-oxido-1:2:3κO;2:3:4κO-tetra-tin(IV).

Ren Yupo Y

Acta crystallographica. Section E, Structure reports online 20110625 Pt 7

In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetra-nuclear complex mol-ecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal-bipyramidal, whilst the two peripheral metal atoms bonded to the carboxyl-ate groups have a distorted octa-hedral coordination geometry. In the crystal, mol-ecules are connected by long Sn⋯O contacts [3.139 (11) Å], forming chains along [011]. ...[more]

PMID: 21836958

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[μ-Bis(diphenyl-phosphan-yl)ethane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-(triphenyl-stibine-3κSb)-triangulo-triruthenium(0).

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