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Toward Production of Pure ¹³C Hyperpolarized Metabolites Using Heterogeneous Parahydrogen-Induced Polarization of Ethyl[1-¹³C]acetate.

ABSTRACT: Here, we report the production of ¹³C-hyperpolarized ethyl acetate via heterogeneously catalyzed pairwise addition of parahydrogen to vinyl acetate over TiO₂-supported rhodium nanoparticles, followed by magnetic field cycling. Importantly, the hyperpolarization is demonstrated even at the natural abundance of ¹³C isotope (ca. 1.1%) along with the easiest separation of the catalyst from the hyperpolarized liquid.

SUBMITTER: Kovtunov KV

PROVIDER: S-EPMC5193475 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature

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Toward Production of Pure ¹³C Hyperpolarized Metabolites Using Heterogeneous Parahydrogen-Induced Polarization of Ethyl[1-¹³C]acetate.

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Toward Production of Pure 13C Hyperpolarized Metabolites Using Heterogeneous Parahydrogen-Induced Polarization of Ethyl[1-13C]acetate.

OmicsDI is part of the ELIXIR infrastructure

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Toward Production of Pure ¹³C Hyperpolarized Metabolites Using Heterogeneous Parahydrogen-Induced Polarization of Ethyl[1-¹³C]acetate.