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Ligand-Induced Shape Transformation of PbSe Nanocrystals.

ABSTRACT: We present a study of the relation between the surface chemistry and nanocrystal shape of PbSe nanocrystals with a variable Pb-to-Se stoichiometry and density of oleate ligands. The oleate ligand density and binding configuration are monitored by nuclear magnetic resonance and Fourier transform infrared absorbance spectroscopy, allowing us to quantify the number of surface-attached ligands per NC and the nature of the surface-Pb-oleate configuration. The three-dimensional shape of the PbSe nanocrystals is obtained from high-angle annular dark field scanning transmission electron microscopy combined with an atom counting method. We show that the enhanced oleate capping results in a stabilization and extension of the {111} facets, and a crystal shape transformation from a truncated nanocube to a truncated octahedron.

SUBMITTER: Peters JL

PROVIDER: S-EPMC5425942 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Ligand-Induced Shape Transformation of PbSe Nanocrystals.

Peters Joep L JL van den Bos Karel H W KHW Van Aert Sandra S Goris Bart B Bals Sara S Vanmaekelbergh Daniël D

Chemistry of materials : a publication of the American Chemical Society 20170406 9

We present a study of the relation between the surface chemistry and nanocrystal shape of PbSe nanocrystals with a variable Pb-to-Se stoichiometry and density of oleate ligands. The oleate ligand density and binding configuration are monitored by nuclear magnetic resonance and Fourier transform infrared absorbance spectroscopy, allowing us to quantify the number of surface-attached ligands per NC and the nature of the surface-Pb-oleate configuration. The three-dimensional shape of the PbSe nanoc ...[more]

PMID: 28503030

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