Ontology highlight
ABSTRACT:
SUBMITTER: Li H
PROVIDER: S-EPMC5431698 | biostudies-literature | 2017 Apr
REPOSITORIES: biostudies-literature
Chemical science 20170104 4
Regioselective difunctionalization of alkenes has attracted significant attention from synthetic chemists and has the advantage of introducing diverse functional groups into vicinal carbons of common alkene moieties in a single operation. Herein, we report an unprecedented intermolecular atom transfer thiosulfonylation reaction of alkenes by combining gold catalysis and visible-light photoredox catalysis. A trifluoromethylthio group (SCF<sub>3</sub>) and other functionalized thio groups together ...[more]