A phase transition caught in mid-course: independent and concomitant analyses of the monoclinic and triclinic structures of (ⁿBu₄N)[Co(orotate)₂(bipy)]·3H₂O.

ABSTRACT: The preparation and characterization of the ⁿBu₄N⁺ salts of two bis-orotate(2-) complexes of cobalt, namely bis(tetra-n-butylammonium) diaquabis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ²N¹,O⁶)cobalt(II) 1.8-hydrate, (C₁₆H₃₆N)₂[Co(C₅H₂N₂O₄)₂(H₂O)₂]·1.8H₂O, (1), and tetra-n-butylammonium (2,2'-bipyridine-κ²N,N')bis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ²N¹,O⁶)cobalt(III) trihydrate, (C₁₆H₃₆N)[Co(C₅H₂N₂O₄)₂(C₁₀H₈N₂)]·3

SUBMITTER: Castro M 

PROVIDER: S-EPMC5601254 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature