Four Mixed-Ligand Zn(II) Three-Dimensional Metal-Organic Frameworks: Synthesis, Structural Diversity, and Photoluminescent Property.

ABSTRACT: Assemblies of four three-dimensional (3D) mixed-ligand coordination polymers (CPs) having formulas, {[Zn₂(bdc)₂(4-bpdh)]·C₂H₅OH·2H₂O}_n (1), [Zn(bdc)(4-bpdh)]_n (2), {[Zn₂(bdc)₂(4-bpdh)₂]·(4-bpdh)}_n (3), and {[Zn(bdc)(4-bpdh)]·C₂H₅OH}_n (4) (bdc^2- = dianion of 1,4-benzenedicarboxylic acid, 4-bpdh = 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene) have been synthesized and structurally characterized by single-crystal X-ray diffraction method. Structural determination reveals that the coordination numbers (geometry) of Zn(II) ions in 1, 2, 3, and 4 are five (distorted square-pyramidal (SP)), six (distorted octahedral (O_h)), five (trigonal-bipyramidal (TBP)), and four (tetr

SUBMITTER: Wang CC 

PROVIDER: S-EPMC6418879 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature