Manganese-Catalyzed Dehydrogenative Silylation of Alkenes Following Two Parallel Inner-Sphere Pathways.

ABSTRACT: We report on an additive-free Mn(I)-catalyzed dehydrogenative silylation of terminal alkenes. The most active precatalyst is the bench-stable alkyl bisphosphine Mn(I) complex fac-[Mn(dippe)(CO)₃(CH₂CH₂CH₃)]. The catalytic process is initiated by migratory insertion of a CO ligand into the Mn-alkyl bond to yield an acyl intermediate which undergoes rapid Si-H bond cleavage of the silane HSiR₃ forming the active 16e^- Mn(I) silyl catalyst [Mn(dippe)(CO)₂(SiR₃)] together with liberated butanal. A broad variety of aromatic and aliphatic alkenes was efficiently and selectively converted into E-vinylsilanes and allylsilanes, respectively, at room temperature. Mechanistic insights are provided bas

SUBMITTER: Weber S 

PROVIDER: S-EPMC8554758 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature