Exploring dopant effects in stannic oxide nanoparticles for CO₂ electro-reduction to formate.

ABSTRACT: The electrosynthesis of formate from CO₂ can mitigate environmental issues while providing an economically valuable product. Although stannic oxide is a good catalytic material for formate production, a metallic phase is formed under high reduction overpotentials, reducing its activity. Here, using a fluorine-doped tin oxide catalyst, a high Faradaic efficiency for formate (95% at 100 mA cm^-2) and a maximum partial current density of 330 mA cm^-2 (at 400 mA cm^-2) is achieved for the electroreduction of CO₂. Furthermore, the formate selectivity (≈90%) is nearly constant over 7 days of operation at a current density of 100 mA cm^-2. In-situ/operando spectroscopies reveal that the fluorine dopant plays a critical role in maintain

SUBMITTER: Ko YJ 

PROVIDER: S-EPMC9033853 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature