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MoS₂ nanosheet mediated ZnO-g-C₃N₄ nanocomposite as a peroxidase mimic: catalytic activity and application in the colorimetric determination of Hg(ii).

ABSTRACT: A novel colorimetric sensing platform using the peroxidase mimicking activity of ternary MoS₂-loaded ZnO-g-C₃N₄ nanocomposites (ZnO-g-C₃N₄/MoS₂) has been developed for the determination of Hg(ii) ions over co-existing metal ions. The nanocomposite was prepared using an exfoliation process, and the product was further characterized using SEM, TEM, XRD and FTIR analysis. The ZnO-g-C₃N₄/MoS₂ possesses excellent intrinsic catalytic activity to induce the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in aqueous solution in the presence of H₂O₂ to generate deep blue coloured cation radicals (TMB⁺) which can be viewed with the naked eye and produce absorbance at a wavelength of 652 nm. The addition of a well known bioradical scavenger, glutathione (GSH), to the solution hinders the generation of cation radicals and turns the solution colourless. The introduction of Hg(ii) to this solution brings the blue colour back into it, due to the strong affinity of the thiol in the GSH. Based on this mechanism, we have developed a simple and rapid colorimetric sensor for the highly sensitive and selective detection of Hg(ii) ions in aqueous solution with a low detection limit of 1.9 nM. Furthermore, the prepared colorimetric sensor was effectively applied for the quantification analysis of real water samples.

SUBMITTER: Babu Christus AA

PROVIDER: S-EPMC9060464 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature

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Publications

MoS2 nanosheet mediated ZnO-g-C3N4 nanocomposite as a peroxidase mimic: catalytic activity and application in the colorimetric determination of Hg(ii).

Babu Christus A Anand AA Panneerselvam P P Ravikumar A A Marieeswaran M M Sivanesan S S

RSC advances 20190101 8

A novel colorimetric sensing platform using the peroxidase mimicking activity of ternary MoS2-loaded ZnO-g-C3N4 nanocomposites (ZnO-g-C3N4/MoS2) has been developed for the determination of Hg(ii) ions over co-existing metal ions. The nanocomposite was prepared using an exfoliation process, and the product was further characterized using SEM, TEM, XRD and FTIR analysis. The ZnO-g-C3N4/MoS2 possesses ...[more]

PMID: 35520178

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Project description:We have synthesized MoS2 incorporated α-Fe2O3/ZnO nanocomposites by adapting a facile hydrothermal synthesis process. The effect of incorporating ultrasonically exfoliated few-layer MoS2 nanosheets on the solar-light driven photocatalytic performance of α-Fe2O3/ZnO photocatalyst nanocomposites has been demonstrated. Structural, morphological and optical characteristics of the as-synthesized nanomaterials are comprehensively investigated and analyzed by performing Rietveld refinement of powder X-ray diffraction patterns, field emission scanning electron microscopy and UV-visible spectroscopy, respectively. The photoluminescence spectra of the as-prepared nanocomposites elucidate that the recombination of photogenerated electron-hole pairs is highly suppressed due to incorporation of MoS2 nanosheets. Notably, the ultrasonicated MoS2 incorporated α-Fe2O3/ZnO nanocomposite manifests 91% and 83% efficiency in degradation of rhodamine B dye and antibiotic ciprofloxacin respectively under solar illumination. Active species trapping experiments reveal that the hydroxyl (˙OH) radicals play a significant role in RhB degradation. Likewise the dye degradation efficiency, the amount of hydrogen produced by this nanocomposite via photocatalytic water splitting is also considerably higher as compared to both non-ultrasonicated MoS2 incorporated α-Fe2O3/ZnO and α-Fe2O3/ZnO nanocomposites as well as Degussa P25 titania nanoparticles. This indicates the promising potential of the incorporation of ultrasonicated MoS2 with α-Fe2O3/ZnO nanocomposites for the generation of carbon-free hydrogen by water splitting. The substantial increase in the photocatalytic efficiency of α-Fe2O3/ZnO after incorporation of ultrasonicated MoS2 can be attributed to its favorable band structure, large surface to volume ratio, effective segregation and migration of photogenerated electron-hole pairs at the interface of heterojunctions and the plethora of exposed active edge sites provided by the few-layer MoS2 nanosheets.

Dataset Information

MoS₂ nanosheet mediated ZnO-g-C₃N₄ nanocomposite as a peroxidase mimic: catalytic activity and application in the colorimetric determination of Hg(ii).

Publications

MoS<sub>2</sub> nanosheet mediated ZnO-g-C<sub>3</sub>N<sub>4</sub> nanocomposite as a peroxidase mimic: catalytic activity and application in the colorimetric determination of Hg(ii).

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