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Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.
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ABSTRACT:
SUBMITTER: Nagata T
PROVIDER: S-EPMC9064576 | biostudies-literature | 2019 May
REPOSITORIES: biostudies-literature
Publications
Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.
RSC advances 20190501 30
<i>N</i>,<i>N</i>-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. <i>N</i>,<i>N-</i>Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can b ...[more]