Crystal structures and electrochemical properties of nickel(II) complexes with N,N',N'',S-tetra-dentate Schiff base ligands.

ABSTRACT: The thiol-ate nickel complexes {2-[({2-[(2-amino-ethyl-κN)(meth-yl)amino-κN]eth-yl}imino-κN)meth-yl]benzene-thiol-ato-κS}nickel(II) chloride, [Ni(C₁₂H₁₈N₃S)]Cl (1), and [2-({[2-(piperazin-1-yl-κ² N ¹,N ⁴)eth-yl]imino-κN}meth-yl)benzene-thiol-ato-κS]nickel(II) hexa-fluoro-phosphate di-chloro-methane monosolvate, [Ni(C₁₃H₁₈N₃S)]PF₆·CH₂Cl₂ (2), were synthesized by the reactions of 2-(tert-butyl-thio)-benzaldehyde, tri-amines, and nickel(II) salts. Both complexes have a nickel ion surrounded by an N,N',N'',S-tetra-dentate ligand, forming a square-planar geometr

SUBMITTER: Hirotsu M 

PROVIDER: S-EPMC9069516 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature