Tandem utilization of CO₂ photoreduction products for the carbonylation of aryl iodides.

ABSTRACT: Photocatalytic CO₂ reduction reaction has been developed as an effective strategy to convert CO₂ into reusable chemicals. However, the reduction products of this reaction are often of low utilization value. Herein, we effectively connect photocatalytic CO₂ reduction and amino carbonylation reactions in series to reconvert inexpensive photoreduction product CO into value-added and easily isolated fine chemicals. In this tandem transformation system, we synthesize an efficient photocatalyst, NNU-55-Ni, which is transformed into nanosheets (NNU-55-Ni-NS) in situ to improve the photocatalytic CO₂-to-CO activity significantly. After that, CO serving as reactant is further reconverted into organic molecules through the coupled carbonylation reactions. Especially in the carbonylation reaction of diethyltoluamide synthesis, CO conversion reaches up to 85%. Meanwhile, this tandem transformation also provides a simple and low-cost method for the ¹³C isotopically labeled organic molecules. This work represents an important and feasible pathway for the subsequent separation and application of CO₂ photoreduction product.

SUBMITTER: Xia YS 

PROVIDER: S-EPMC9135707 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature