Titanium(IV) Oxo-Complex with Acetylsalicylic Acid Ligand and Its Polymer Composites: Synthesis, Structure, Spectroscopic Characterization, and Photocatalytic Activity.

ABSTRACT: The titanium oxo complexes are widely studied, due to their potential applications in photocatalytic processes, environmental protection, and also in the biomedical field. The presented results concern the oxo complex synthesized in the reaction of titanium(IV) isobutoxide and acetylsalicylic acid (Hasp), in a 4:1 molar ratio. The structure of isolated crystals was solved using the single-crystal X-ray diffraction method. The analysis of these data proves that [Ti₄O₂(OⁱBu)₁₀(asp)₂]·H₂O (1) complex is formed. Moreover, the molecular structure of (1) was characterized using vibrational spectroscopic techniques (IR and Raman), ¹³C NMR, and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). The photoc

SUBMITTER: Smigiel J 

PROVIDER: S-EPMC9267303 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature