CsCu₂I₃ Nanoparticles Incorporated within a Mesoporous Metal-Organic Porphyrin Framework as a Catalyst for One-Pot Click Cycloaddition and Oxidation/Knoevenagel Tandem Reaction.

ABSTRACT: Metal-organic frameworks (MOFs) and metal halide perovskites are currently under much investigation due to their unique properties and applications. Herein, an innovative strategy has been developed combining an iron-porphyrin MOF, PCN-222(Fe), and an in situ-grown CsCu₂I₃ nontoxic lead-free halide perovskite based on an earth-abundant metal that becomes incorporated within the MOF channels [CsCu₂I₃@PCN-222(Fe)]. Encapsulation was designed to decrease and control the particle size and increase the stability of CsCu₂I₃. The hybrid materials were characterized by various techniques including FE-SEM, elemental mapping and line scanning EDX, TEM, PXRD, UV-Vis DRS, BET surface area, XPS, and photoemission measurements. Hyb

SUBMITTER: Daliran S 

PROVIDER: S-EPMC9940116 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature