Forming Bonds While Breaking Old Ones: Isomer-Dependent Formation of H₃O⁺ from Aminobenzoic Acid During X-ray-Induced Fragmentation.

ABSTRACT: Intramolecular hydrogen transfer, a reaction where donor and acceptor sites of a hydrogen atom are part of the same molecule, is a ubiquitous reaction in biochemistry and organic synthesis. In this work, we report hydronium ion (H₃O⁺) production from aminobenzoic acid (ABA) after core-level ionization with soft X-ray synchrotron radiation. The formation of H₃O⁺ during the fragmentation requires that at least two hydrogen atoms migrate to one of the oxygen atoms within the molecule. The comparison of two structural isomers, ortho- and meta-ABA, revealed that the production of H₃O⁺ depends strongly on the structure of the molecule, the ortho-isomer being much more prone to produce H₃O⁺. The isomer-depende

SUBMITTER: Abid AR 

PROVIDER: S-EPMC9940210 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature