Unknown

Dataset Information

0

Aqua-bis-(2,2'-bi-pyridine-κ2N,N')(isonicotinamide-κN)ruthenium(II) bis-(trifluoromethanesulfonate).

ABSTRACT: In the title complex, [Ru(C10H8N2)2(C6H6N2O)(H2O)](CF3SO3)2, the central RuII atom is sixfold coordinated by two bidentate 2,2'-bi-pyridine, an isonic-otinamide ligand, and a water mol-ecule in a distorted octa-hedral environment with tri-fluoro-methane-sulfonate ions completing the outer coordination sphere of the complex. Hydrogen bonding involving the water mol-ecule and weak π-π stacking inter-actions between the pyridyl rings in adjacent mol-ecules contribute to the alignment of the complexes in columns parallel to the c axis.

SUBMITTER: Faubert L 

PROVIDER: S-EPMC10915547 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Aqua-bis-(2,2'-bi-pyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')(isonicotinamide-κ<i>N</i>)ruthenium(II) bis-(trifluoromethanesulfonate).

Faubert Liam L   Arman Hadi D HD   Adrian Rafael A RA  

IUCrData 20240208 Pt 2

In the title complex, [Ru(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>(C<sub>6</sub>H<sub>6</sub>N<sub>2</sub>O)(H<sub>2</sub>O)](CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, the central Ru<sup>II</sup> atom is sixfold coordinated by two bidentate 2,2'-bi-pyridine, an isonic-otinamide ligand, and a water mol-ecule in a distorted octa-hedral environment with tri-fluoro-methane-sulfonate ions completing the outer coordination sphere of the complex. Hydrogen bonding involving the water mol-e  ...[more]

Similar Datasets

Unknown Crystal structure of bis-(2,2'-bi-pyridine-κ(2) N,N')bis-(thio-cyanato-κN)mang-anese(II) 2,2'-bi-pyridine monosolvate.
| S-EPMC4331911 | biostudies-literature
Unknown Di-μ-aqua-bis-[aqua-(2,2'-bi-pyridine)(4-nitro-benzoato)cobalt(II)] bis-(4-nitro-benzoate).
| S-EPMC9462235 | biostudies-literature
Unknown (2,2'-Bi-pyridine-κ(2) N,N')bis-(nitrato-κ(2) O,O')copper(II).
| S-EPMC3884263 | biostudies-literature
Unknown Crystal structure of cis-aqua-bis-(2,2'-bi-pyridine-κ(2) N,N')chlorido-chromium(III) tetra-chlorido-zincate determined from synchrotron data.
| S-EPMC4778834 | biostudies-literature
Unknown Diaceto-nitrile-(2,2'-bi-pyridine-κ<sup>2</sup> <i>N</i>,<i>N</i>')palladium(II) bis-(tri-fluoro-methane-sulfonate).
| S-EPMC9815130 | biostudies-literature
Unknown Crystal structure of bis-(μ-2-benzoyl-benzoato-κ(2) O:O')bis-[bis-(2,2'-bi-pyridine-κ(2) N,N')manganese(II)] bis-(perchlorate).
| S-EPMC4719866 | biostudies-literature
Unknown (2,2'-Bi-pyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')(4,4'-dimeth-oxy-2,2'-bipyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')palladium(II) bis-(tri-fluoro-meth-anesulfonate).
| S-EPMC10915546 | biostudies-literature
Unknown Crystal structure of (2,2'-bi-pyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')bis-(3,5-di-<i>tert</i>-butyl-<i>o</i>-benzo-quinonato-κ<sup>2</sup><i>O</i>,<i>O</i>')ruthenium(II).
| S-EPMC5347077 | biostudies-literature
Unknown Bis(2,2'-bipyridine){ethyl 4'-[N-(4-carbamoylphen-yl)carbamo-yl]-2,2'-bi-pyridine-4-carboxyl-ate}ruthenium(II) bis-[hexa-fluorido-phosphate(V)].
| S-EPMC2968400 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of tetra-aqua-bis-(isonicotinamide-κ<i>N</i> <sup>1</sup>)nickel(II) fumarate.
| S-EPMC6218910 | biostudies-literature