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Enantioselective total synthesis of spirofungins A and B.

ABSTRACT: The enantioselective total synthesis of spirofungins A (1) and B (2) is reported in 14 steps over the longest linear sequence. Key steps include the use of thiazolidinethione-mediated aldol reactions to assemble the major fragments and installation of the C1-C6 side chain using a cross metathesis reaction.

SUBMITTER: Crimmins MT 

PROVIDER: S-EPMC2950280 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Enantioselective total synthesis of spirofungins A and B.

Crimmins Michael T MT   O'Bryan Elizabeth A EA  

Organic letters 20101001 19

The enantioselective total synthesis of spirofungins A (1) and B (2) is reported in 14 steps over the longest linear sequence. Key steps include the use of thiazolidinethione-mediated aldol reactions to assemble the major fragments and installation of the C1-C6 side chain using a cross metathesis reaction. ...[more]

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