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Dynamic propeller conformation for the unprecedentedly high degree of chiral amplification of supramolecular helices.

ABSTRACT: An unprecedentedly high degree of chiral amplification of supramolecular helices in a sergeants and soldiers system was realized using a propeller-shaped molecule, triphenylamine (TPA), as the monomer. One sergeant controlled the handedness of 500 soldiers in supramolecular helices. We further demonstrated that a TPA derivative could switch its role from sergeant to soldier and vice versa depending on its partners. These achievements could be realized using the dynamic propeller conformation of TPA and provide new insights into supramolecular assemblies and the supramolecular chiral amplification of helices.

SUBMITTER: Kim T

PROVIDER: S-EPMC5355865 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature

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Dynamic propeller conformation for the unprecedentedly high degree of chiral amplification of supramolecular helices.

Kim Taehoon T Mori Tadashi T Aida Takuzo T Miyajima Daigo D

Chemical science 20160712 11

An unprecedentedly high degree of chiral amplification of supramolecular helices in a sergeants and soldiers system was realized using a propeller-shaped molecule, triphenylamine (TPA), as the monomer. One sergeant controlled the handedness of 500 soldiers in supramolecular helices. We further demonstrated that a TPA derivative could switch its role from sergeant to soldier and <i>vice versa</i> depending on its partners. These achievements could be realized using the dynamic propeller conformat ...[more]

PMID: 28451111

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