Photoinduced metal-free borylation of aryl halides catalysed by an in situ formed donor-acceptor complex.

ABSTRACT: Organoboron compounds are very important building blocks which can be applied in medicinal, biological and industrial fields. However, direct borylation in a metal free manner has been very rarely reported. Herein, we described the successful direct borylation of haloarenes under mild, operationally simple, catalyst-free conditions, promoted by irradiation with visible light. Mechanistic experiments and computational investigations indicate the formation of an excited donor-acceptor complex with a -3.12 V reduction potential, which is a highly active reductant and can facilitate single-electron-transfer (SET) with aryl halides to produce aryl radical intermediates. A two-step one-pot method was developed for site selective aromatic C-H bond borylation. The protocol's good functional group

SUBMITTER: Li M 

PROVIDER: S-EPMC9067585 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature