On the Thermochemical Transition Depression of Cellulose Acetate Composite Membranes.

ABSTRACT: Gallic acid (GA) and quercetin (QU) are two important bioactive molecules with increased biomedical interest. Cellulose acetate (CA) is a polymer derived from cellulose and is used in various applications. In this work, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FTIR) were used to study the thermal behavior of electrospun CA membranes loaded with quercetin or gallic acid. It was found that gallic acid and quercetin depress the thermochemical transition (simultaneous softening and decomposition) of CA, in a mechanism similar to that of the glass transition depression of amorphous polymers by plasticizers. The extensive hydrogen bonding, besides the well-known effect of constraining polymer's softening by keeping mac

SUBMITTER: Tsioptsias C 

PROVIDER: S-EPMC9416459 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature