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Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols.

ABSTRACT: Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability ≈1000% and strength ≈3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.

SUBMITTER: de Lacalle JL

PROVIDER: S-EPMC9948532 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols.

de Lacalle Jon López JL Gallastegui Antonela A Olmedo-Martínez Jorge L JL Moya Melissa M Lopez-Larrea Naroa N Picchio Matías L ML Mecerreyes David D

ACS macro letters 20230112 2

Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with den ...[more]

PMID: 36633542

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