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(?2-Adipato-?4O,O':O'',O''')bis-[aqua-(benzene-1,2-di-amine-?2N,N')-chlorido-cadmium]: crystal structure and Hirshfeld surface analysis.

ABSTRACT: The full mol-ecule of the binuclear title compound, [Cd2Cl2(C6H8O4)(C6H8N2)2(H2O)2], is generated by the application of a centre of inversion located at the middle of the central CH2-CH2 bond of the adipate dianion; the latter chelates a CdII atom at each end. Along with two carboxyl-ate-O atoms, the CdII ion is coordinated by the two N atoms of the chelating benzene-1,2-di-amine ligand, a Cl- anion and an aqua ligand to define a distorted octa-hedral CdClN2O3 coordination geometry with the monodentate ligands being mutually cis. The disparity in the Cd-N bond lengths is related to the relative trans effect exerted by the Cd-O bonds formed by the carboxyl-ate-O and aqua-O atoms. The packing features water-O-H?O(carboxyl-ate) and benzene-1,2-di-amine-N-H?Cl hydrogen bonds, leading to layers that stack along the a-axis direction. The lack of directional inter-actions between the layers is confirmed by a Hirshfeld surface analysis.

SUBMITTER: Rahman WSKA 

PROVIDER: S-EPMC5588581 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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(μ<sub>2</sub>-Adipato-κ<sup>4</sup><i>O</i>,<i>O</i>':<i>O</i>'',<i>O</i>''')bis-[aqua-(benzene-1,2-di-amine-κ<sup>2</sup><i>N</i>,<i>N</i>')-chlorido-cadmium]: crystal structure and Hirshfeld surface analysis.

Rahman Wannur Sofiasalamah Khairiah A WSKA   Ahmad J J   Halim Siti Nadiah Abdul SNA   Jotani Mukesh M MM   Tiekink Edward R T ERT  

Acta crystallographica. Section E, Crystallographic communications 20170821 Pt 9

The full mol-ecule of the binuclear title compound, [Cd<sub>2</sub>Cl<sub>2</sub>(C<sub>6</sub>H<sub>8</sub>O<sub>4</sub>)(C<sub>6</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>], is generated by the application of a centre of inversion located at the middle of the central CH<sub>2</sub>-CH<sub>2</sub> bond of the adipate dianion; the latter chelates a Cd<sup>II</sup> atom at each end. Along with two carboxyl-ate-O atoms, the Cd<sup>II</sup> ion is coordinated by the tw  ...[more]

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